Air pollution control


[Published in the 1983 Edition of the Encyclopaedia of Occupational Health and Safety, Volume 1, p. 97-102. Paper is posted for reference purposes, recognizing that in the last 40 years there was considerable development in this area, and some information will necessarily be outdated.]


Air pollution control aims at the elimination, or reduction to acceptable levels, of agents (e.g. gaseous materials, particulate matter, physical agents and, up to a certain extent, biological agents), whose presence in the atmosphere can cause adverse effects on human health or welfare (e.g. irritation, cancer, odors, interference with visibility, etc.), deleterious effects on animal or plant life, damage to materials of economic value to society and damage to the environment (e.g. climatic modifications). The serious hazards associated with radioactive pollutants, as well as the special procedures required for their control and disposal, deserve careful attention (see RADIOACTIVE WASTE MANAGEMENT).


The importance of efficient air pollution control cannot be overemphasized. Unless there is adequate control, the multiplication of pollution sources in the modern world may lead to irreparable damage to the environment and mankind International agencies such as the World Health Organization, the World Meteorological Organization and the United Nations Environment Programme have instituted monitoring and research projects in order to clarify the issues involved in air pollution and to promote measures to prevent further deterioration of environmental and climatic conditions The objective of this article is to give a general overview


of the possible approaches to the control of air pollution particularly from industrial sources. Industrial air pollution starts at the workplace, therefore it is there that its control should start. There are many analogies and there should be close coordination between in-plant and community air pollution control: many preventive measures can solve both problems at the same time. However, air pollution control involves consideration of additional factors, such as topography and meteorology. pollution sources. community and mobile government participation, among many others, all of which must be integrated into a comprehensive prog programme. For example, meteorological conditions can greatly affect the ground-level concentrations resulting from the same pollutant emission. Besides, air pollution sources may be scattered over a community or a region and their effects may be felt by, or their control may involve, more than one administration. Air pollution control requires a multi-disciplinary approach as well as a joint effort by different entities, private and governmental.


Sources of air pollution


The sources of man-made air pollution (or emission) sources) are of basically two types.

(1) Stationary, which can be subdivided into

(a) industrial, e.g. factories, mills, power plants, mines and quarries, refineries, cement plants, industrial incinerators:

(b) community, e.g. heating of homes and buildings, incinerators, fireplaces, cooking facilities,

(2) Mobile, comprising any form of combustion engine vehicles, e.g. automobiles, planes, trains.


There are also natural sources of pollution, e.g. certain plants which release great amounts of pollen, sources of bacteria, spores and viruses, etc. Physical, biological and vegetable agents are not discussed in this article.


Types of air pollutants


Air pollutants are usually classified into particulate matter (dusts, fumes, mists, smokes), gaseous pollutants (gases and vapors) and odors. Although types of air pollution are discussed under AIR POLLUTION, Some examples of usual pollutants are presented in what follows.


Particulate matter: coal fly-ash, mineral dusts (e.g. coal, asbestos, limestone, cement). metal dusts and fumes (e.g. zinc, copper, iron, lead), acid mists (e.g. sulphuric acid), fluorides, paint pigments, pesticide mists, carbon black, tobacco smoke, oil smoke, etc.


Particulate pollutants, besides their effects of corrosion, toxicity, irritation, carcinogenicity, destruction to plant life, etc., can also act as a nuisance (e.g. accumulation of dirt), interfere with sunlight (e.g. formation of smog and haze due to light scattering) and. also, act as catalytic surfaces for reaction of adsorbed chemicals.


Gaseous pollutants: sulfur compounds (e.g. SO2 and SO), carbon monoxide, nitrogen compounds (e.g. nitric oxide, nitrogen dioxide, ammonia), organic compounds (e.g. hydrocarbons including polycyclic aromatic hydrocarbons and halogen derivatives, aldehydes, etc.), halogen compounds (HF and HCI), hydrogen sulfide, carbon disulphide and mercaptans (odors).


Secondary pollutants may be formed by thermal, chemical or photochemical reactions. For example, by thermal action sulfur dioxide can oxidize to sulfur trioxide which, dissolved in water, gives rise to the formation of sulphuric acid mist (catalyzed by manganese and iron oxides) Photochemical reactions between nitrogen oxides and reactive hydrocarbons can produce ozone, formaldehyde and peroxyacetyl nitrate: reactions between HCI and formaldehyde can form bis chloromethyl ether.


Odors: While some odors are known to be caused by specific chemical agents such as hydrogen sulfide, carbon disulphide and mercaptans, others are difficult to define chemically. Examples of the main pollutants associated with some industrial air pollution sources are presented in table 1.